曹堃课题组

您的位置:曹堃课题组 > 教师

 
姚臻 博士,教授,博导

杭州市浙大路38号,浙江大学化工系
电话:0571-87951832O
传真:0571-87951832
电子邮件:
yaozhen@zju.edu.cn 
简历
 
2011-现在: 教授,博导,聚合及聚合物工程研究所,化工系, 浙江大学, 杭州, 浙江, 中国
2004-2011 副教授,聚合及聚合物工程研究所,化工系, 浙江大学, 杭州, 浙江, 中国
2003           Research Scientist, 杜邦加拿大研发中心, Kingston, Ontario, Canada
2002           Research Scientist,, 汽车材料与制造中心, Kingston, Ontario, Canada
2001           Research Scientist(兼职), 杜邦加拿大研发中心, Kingston, Ontario, Canada
2000-2001 博士后, 化工系, Queen's University, Kingston, Ontario, Canada
1998-1999 博士后, 化工系, University of Wisconsin, Madison, Wisconsin, USA
1993-1998 博士研究生, 化工系, 浙江大学, 杭州, 浙江, 中国
 
学术荣誉
 
长期从事化工过程及高分子材料的研究,先后负责承担国家自然科学基金、国家重点基础研究发展计划(973计划)项目、国家高技术研究发展计划(863计划)、企业横向项目等十余项研究课题,在SCI刊物上发表论文50余篇,获中国发明专利授权11项。
 
学术兼职
 
²  Energy & FuelsIndustrial & Engineering Chemistry ResearchMacromoleculesPolymerJournal of Applied Polymer Science、化工学报等期刊的审稿人
²  国家自然科学基金及多省市自然科学基金的评阅人
²  浙江省化工学会第十届高分子专业委员会秘书长
²  履行《禁止化学武器公约》浙江省工作组专家
 
研究兴趣
 
1.   绿色化工方法强化高粘化工过程、控制特种材料的结构及性能
2.   发泡聚合物形态控制及能量捕集材料制备
3.   缩聚高分子工程材料的生产过程、结构控制及性能研究
4.   特种烯烃单体的合成、聚合及高附加值聚合物材料的结构、性能调控
 
主要研究项目
 
1.   采用点击化学的反应挤出过程研究(国家自然科学基金)
2.   原油降凝剂的结构设计、控制及其性能研究(国家自然科学基金)
3.   原位橡塑合金颗粒化制备工艺及关键共性技术研究(863
4.   聚丙烯-氟聚物定向复合的孔洞型压电材料结构设计、制备过程及性能研究(教育部博士点基金)
5.   高乙烯含量共聚聚丙烯新牌号及相关工业装置开发(横向项目)
6.   环烯共聚物及其所用单体的制备(横向项目)
7.   超临界技术制备高分子量脂肪族酯-半芳香族酰胺共聚物及其结构调控(国家自然科学基金,已结题)
8.   基于过程模型的生产全流程在线动态运行优化理论和方法研究(973,已结题)
9.   基于PACM的尼龙合成过程基本特征研究(横向项目,已结题)                        
10. 乙叉降冰片烯合成的模试研究及2000吨规模工艺包设计(横向项目,已结题)
 
论文及专著
 
1.         J.Z. Weng, Z.J. Shao, X. Chen, X.P. Gu, Z. Yao, L.F. Feng, L.T. Biegler, “A Novel Strategy for Dynamic Optimization of Grade Transition Processes Based on Molecular Weight Distribution”, AIChE J., 2014, v60(7), 2498-2512.
2.         Z.H. Chen, C.C. Zeng, Z. Yao and K. Cao, "Solid-State Foaming of Cyclic Olefin Copolymer by Carbon Dioxide", Ind. Eng. Chem. Res., 2013, v52(27), 9381-9396.
3.         Y. Li, Z. Yao, Z.H. Chen, S.L. Qiu, C.C. Zeng and K. Cao, "Rheological Evidence of Physical Cross-Links and Their Impact in Modified Polypropylene", Ind. Eng. Chem. Res., 2013, v52(23), 7758-7767.
4.         C. Zhang, Z.L. Zhan, Z.J. Shao, Y.H. Zhao, X. Chen, X.P. Gu, Z. Yao, L.F. Feng and L.T. Biegler, "Equation-Oriented Optimization on an Industrial High-Density Polyethylene Slurry Process with Target Molecular Weight Distribution", Ind. Eng. Chem. Res., 2013, v52(22), 7240-7251.
5.         S.K. Huang, J.Y. Jin, Y.X. Guan, Z. Yao, K. Cao and S.J. Yao, "Refolding of recombinant human interferon gamma inclusion bodies in vitro assisted by colloidal thermo-sensitive poly(N-isopropylacrylamide) brushes grafted onto the surface of uniform polystyrene cores", Biochem. Eng. J., 2013, v74, 20-26.
6.         L. Chen, X. Chen, J.X. Qian, Z. Yao and Ieee, "A New Method for Parameter Identifiability of DAE systems", in 2013 10th IEEE International Conference on Control and Automation. New York.280-283.
7.         K. Cao, X.X. Wei, B.J. Li, J.S. Zhang, Z. Yao, "Study on influence of imidization degree of poly(styrene-co-octadecyl maleimide) as waxy crude oil flow improvers" , Energy & Fuels, 2013, v27(2), 640-645. 2013/2/21.
8.         Z.Q. Chen, X. Chen*, Z.J. Shao, Z. Yao and L.T. Biegler,"Parallel calculation methods for molecular weight distribution of batch free radical polymerization". Comput. Chem. Eng., 2013, 48(1), 175-186.
9.         K. Cao, S.L. Wu, S.L. Qiu, Y. Li and Z. Yao, "Synthesis of N-Alkoxy Hindered Amine Containing Si lane as a Multifunctional Flame Retardant Synergist and Its Application in Intumescent Flame Retardant Polypropylene", Ind. Eng. Chem. Res., 2013, v52(1), 309-317.
10.      Z.H. Chen, C.C. Zeng, C. Zhang, B. Wang, K. Cao and Z. Yao, "Preparation and properties of cyclic olefin copolymers multiwalled carbon nanotube nanocomposites", J. Appl. Poly. Sci., 2012, v126(3),1121-1128.
11.      , 付强, 周立武, 姚臻, "双环戊二烯反应注塑", 化学进展, 2012, v24(07),1368-1377.
12.      Z. Yao, J.M. Sun, Q. Wang, G.D. Zhou and K. Cao, "Monte Carlo simulation of molecular weight distribution and copolymer composition in transamidation reaction of polyamides", J. Appl. Poly. Sci., 2012, v125(5),3582-3590.
13.      Z. Yao, L.W. Zhou, B.B. Dai and K. Cao, "Ring-opening metathesis copolymerization of dicyclopentadiene and cyclopentene through reaction injection molding process", J. Appl. Poly. Sci., 2012, v125(4),2489-2493.
14.      K. Cao, Q. Wang, Y.C. Zhou, J.M. Sun and Z. Yao, "Crystallization Behavior of Reactive Blends between PBS and PA6IcoT", Ind. Eng. Chem. Res., 2012, v51(15),5461-5468.
15.       Z. Yao, J.M. Sun, Q. Wang and K. Cao, "Study on Ester-Amide Exchange Reaction between PBS and PA6IcoT", Ind. Eng. Chem. Res., 2012, v51(2),751-757.
16.      K. Cao, Y. Li, Z. Yao, G.D. Zhou, C.C. Zeng and Z.M. Huang, "Morphology evolution of miscible blends between crystalline PA6 and amorphous PA6IcoT"J. Appl. Poly. Sci., 2012, v124(2),1447-1455.
17.      K. Cao, Y. Li, Z.Q. Lu, S.L. Wu, Z.H. Chen, Z. Yao, and Z.M. Huang, "Preparation and Characterization of High Melt Strength Polypropylene with Long Chain Branched Structure by the Reactive Extrusion Process”, J. Appl. Poly. Sci., 2011,v121(6), 3384-3392.
18.      Y. Li, Z. Yao, Z.H. Chen, K. Cao, S.L. Qiu, F.J. Zhu, C.C. Zeng, and Z.M. Huang, “Numerical Simulation of Polypropylene Foaming Process Assisted by Carbon Dioxide: Bubble Growth Dynamics and Stability”, Chem. Eng. Sci., 2011,v66(16), 3656-3665.
19.      Z. Yao, J.S. Zhang, Y.Y. Lu, B.J. Li, W.M. Yu, and K. Cao,“Preparation of Well-defined Block Copolymer having One Polystyrene Segment and Another Poly(Styrene-alt-Maleic anhydride) Segment with RAFT Polymerization” , J. Appl. Poly. Sci.,2011, v121(3), 1740-1746. 5 August
20.      S.J. Liu, Z. Yao, L. Chen, B.B. Dai, K. Cao, B.G. Li, and S.P. Zhu, “Influence of chain microstructure on ethylene-norbornene copolymer film properties”, J. Appl. Poly. Sci., 2011, v121(2), 707-710.
21.      , 吴水良, 李彦, 朱方君, 姚臻, “N-取代烷氧基受阻胺类阻燃剂的最新进展及其在聚烯烃中的应用”,化学进展, 2011, v23(6), 1189-1195.
22.      K. Cao,S.L. Wu, K.L Wang, and Z. Yao,Kinetic Study on Surface Modification of Ammonium Polyphosphate with Melamine”, Ind. Eng. Chem. Res., 2011, v50(14), 8402-8406.
23.      Z. Yao, F.J. Zhu, Z.H. Chen, C.C. Zeng, and K. Cao, “Solubility of Subcritical and Supercritical Propylene in Semicrystalline Polypropylene”, J. Chem. & Eng. Data, 2011, v56(4), 1174–1177.
24.      Z. Yao, H.J. Chen, Y.X. Qin, and K. Cao, “Effect of pH Value on the Aqueous Precipitation Copolymerization of Acrylonitrile and Vinyl Acetate”, J. Appl. Poly. Sci.,2011, v119(3), 1486-1491.  
25.      姚臻, 戴斌斌, 刘少杰, , 傅建松, 谢家明, “乙烯和降冰片烯加成共聚合催化体系”,  化学进展, 2010, v22(10), 2024-2032.
26.      姚臻, 戴斌斌, 刘少杰, , 谢家明, 傅建松, 孙荣华, “极性环烯烃共聚物的研究进展”, 高分子材料科学与工程, 2010, v26(6), 162-166.
27.      H.Y. Liu, Z. Yao, K. Cao, and B.G. Li, “Kinetics Analysis for the Imidization of Poly(styrene-co-maleic anhydride) with Aniline in Melt”, J. Appl. Poly. Sci., 2010, v116(5), 2951-2957.
28.      Z.H. Chen, Z. Yao, F.J. Zhu, K. Cao, Y. Li, and Z.M. Huang,  "Gas-Liquid Critical Properties of Ethylene + Hydrogen and Propylene + Hydrogen Binary Mixtures", J. Chem. & Eng. Data, 2010, v55(5), 2004-2007.
29.      H.Y. Liu, Z. Yao, K. Cao, and B.G.Li, “Characteristic Analysis on a Reactive Extrusion Process for the Imidization of Poly(styrene-co-maleic anhydride) with Aniline, Chem. Eng. Sci., 2010,  v65(5), 1781-1789.
30.      K. Cao, Z.C. Shen, Z. Yao, B.W. Qu, X.B. Pang, Z.Q. Lu, Y. Li, and Z.H. Chen, New Insight into the Action of Supercritical Carbon Dioxide for Grafting of Maleic Anhydride onto Isotactic Polypropylene by Reactive Extrusion, Chem. Eng. Sci., 2010, v65(5), 1621-1626.
31.      S.J. Liu, K. Cao, Z. Yao, B.G. Li and S.P. Zhu, “Model Development for Semicontinuous Production of Ethylene and Norbornene Copolymers Having Uniform Composition”, AIChE J., 2009, v55(3), 663-674.
32.      Z.H. Chen, Z. Yao, Y. Li, K. Cao, and Z.M. Huang, “Prediction of Vapor-Liquid Equilibrium at High-Pressure using a New Excess Free Energy Mixing Rule Coupled with the Original UNIFAC and the SRK Equation of State”, Ind. Eng. Chem. Res., 2009, v48(14), 6836-6845.
33.      X. Chen, L. Chen, J. Feng, Z. Yao, and J.X. Qian, “Toward Polymer Product Design. I. Dynamic Optimization of Average Molecular Weights and Polydispersity Index in Batch Free Radical Polymerization”, Ind. Eng. Chem. Res., 2009, v48(14), 6739-6748.
34.      S.J. Liu, Z. Yao, K. Cao, B.G. Li and S.P. Zhu, “Preparation of Polar Ethylene–Norbornene Copolymers by Metallocene Terpolymerization with Triisobutylaluminium-Protected But-3-en-1-ol”, Macromol. Rapid Comm., 2009, v30(7), 548-553.
35.      Z.H. Chen, K. Cao, Z. Yao and Z.M. Huang, “Modeling Solubilities of Subcritical and Supercritical Fluids in Polymers with Cubic and Non-cubic Equations of State”, J. Supercrit. Fluid, 2009, v49(2), 143-153.
36.      X. Ge, Y.X. Guan, J. Chen, Z. Yao, K. Cao, and S.J. Yao, “Refolding of Lysozyme in vitro Assisted by Colloidal Thermo-sensitive Poly(N-isopropylacrylamide) Brushes Grafted onto the Surface of Uniform Polystyrene Cores”, J. Appl. Poly. Sci., 2009, v114(2), 1270-1277.
37.      S.J. Liu, Z. Yao and K. Cao, “Comparison of Thermal Properties of Ethylene-Norbornene Copolymers Prepared by Batch and Semi-batch Processes”, J. Appl. Poly. Sci., 2009, v112(4), 2493-2496.
38.      Z. Yao, Z.Q. Lu, X. Zhao, B.W. Qu, Z. C. Shen and K. Cao, “Synthesis and Characterization of Polypropylene Grafting High Density Polyethylene via Macromolecular Reaction and their Rheological Behavior”, J. Appl. Poly. Sci., 2009, v111(5), 2553-2561.
39.      周光大, 姚臻, , 李伯耿, “PA6/PA6IcoT相容共混物的结晶行为”, 高分子材料科学与工程, 2009, v25(9), 101-104.
40.      Z. Yao, S.J. Liu, F. Lv and K. Cao, “Determination of Mark-Houwink Parameters of Ethylene-Norbornene Copolymers and Molecular Characteristics Estimation”, J. Appl. Poly. Sci., 2008, v109(6), 4010-4014.
41.      Z. Yao, F. Lv, S.J. Liu and K. Cao, “Synthesis of Ethylene and Norbornene Copolymer with Metallocene Catalysts and Characteristic Analysis”, J. Appl. Poly. Sci., 2008, v107(1), 286-291.
42.      , 姚臻,李伯耿, “高分子材料的反应加工(14超临界技术在聚烯烃反应挤出中的应用)”,殷敬华主编, 科学出版社专著, 2008, 612-646.
43.      , 秦一秀, 姚臻, “腈纶阻燃研究进展, 高分子材料科学与工程, 2008, v24(9), 1-5.
44.      H.Y. Liu, K. Cao, Z. Yao, B.G. Li and G.H. Hu, “Variations of the Glass-Transition Temperature in the Imidization of Poly(styrene-co-maleic anhydride)”, J. Appl. Poly. Sci., 2007, v104(4), 2418-2422.
45.      W. Zheng,  K.B. McAuley, E.K. Marchildon and Z. Yao, “Melt-Phase Nylon 612 Polycondensation Kinetics: Effects of Sodium Hypophosphite Catalyst”, Canadian J. Chem. Eng., 2007, v85(2), 180-187. April
46.      陈振华, , 姚臻, 范荣, 黄志明, “超临界烯烃聚合的研究进展—Ⅱ、相行为, 高分子材料科学与工程, 2007, v23 (1), 11-15.
47.      , 王开立, , “聚磷酸铵的改性及其对聚丙烯阻燃特性的研究”, 高分子材料科学与工程, 2007, v23(4), 136-139.
48.      H.Y. Liu, K. Cao, Y. Huang, Z. Yao, B.G. Li and G.H. Hu, “Kinetics and Simulation of the Imidization of Poly(styrene-co-maleic anhydride) with Amines”, J. Appl. Poly. Sci., 2006, v100(4), 2744-2749.
49.      周光大, , 姚臻, 李伯耿, 胡国华, “同向双螺杆挤出机的停留时间分布及填充度”, 化工学报, 2006, v57(12), 3025-3028.
50.      , 霍志宏, 姚臻, 王齐, 范荣, 王兴仁, 杨爱武, 笪文忠, 柏基业, 姚小利, 尤侯平, “超临界聚合法等规聚丙烯的结晶行为”, 高分子材料科学与工程, 2005, v21(6), 110-112, 117. 2005-11
51.      , 杨明涛, 姚臻, “聚苯乙烯微球表面温敏性毛发特性研究”, 高分子材料科学与工程, 2005, v21(5), 278-281. 2005-09
52.      尤侯平, , 范荣, 霍志宏, 姚小利, 王齐, 柏基业, 笪文忠, 杨爱武, 王兴仁, 姚臻, 梅利, 陈振华, “超临界烯烃聚合的研究进展、聚合工艺及工业应用”, 高分子材料科学与工程, 2005, v21(4), 37-41. 2005-07
53.      W. Zheng,  K.B. McAuley, E.K. Marchildon andK.Z. Yao, “Effects of End-Group Balance on Melt-Phase Nylon 612 Polycondensation:  Experimental Study and Mathematical Model”,  Ind. Eng. Chem. Res., 2005, v44(8),  2675-2686.
54.      B. Kou, K. B.McAuley, C.C.Hsu, D.Bacon and K.Z. Yao, "Gas-Phase Ethylene/Hexene Copolymerization with Metallocene Catalyst in a Laboratory-Scale Reactor”, Ind. Eng. Chem. Res., 2005, v 44(8), 2443-2450.
55.      B. Kou, K. B.McAuley, C.C.Hsu, D.Bacon and K. Z. Yao,Mathematical Model and Parameter Estimation for Gas-Phase Ethylene Homopolymerization with Supported Metallocene Catalys”, Ind. Eng. Chem. Res., 2005, v 44(8),  2428-2442.
56.      J. E. Puskas, S. Shaikh, K.Z. Yao,K.B. McAuley, andG. Kaszas, “Kinetic Simulation of Living Carbocationic Polymerizations. II. Simulation of Living Isobutylene Polymerization Using A Mechanistic Model”, European Polymer J., 2005, v41(1), 1-14. 
57.      K.Z. Yao, K. Karan, K. B. McAuley, P. Oosthuizen, B. Peppley and T.Y. Xie, A Review of Mathematical Models for Hydrogen and Direct Methanol Polymer Electrolyte Membrane Fuel Cells”, Fuel Cells, 2004, v4(1-2), 3-29.
58.      K.Z. Yao, B. Shaw, B. Kou, K.B. McAuley and D. Bacon, "Modeling Ethylene/Butene Copolymerization with Multi-site Catalysts: Parameter Estimibility and Experimental Design “, Polymer Reac. Eng., 2003, v11(3), 563-588.
59.      K.Z. Yao, K.B. McAuley and E.K. Marchildon, Simulation of Continuous Solid- Phase Polymerization of Nylon 6,6 (III): Simplified Model, J. Appl. Poly. Sci., 2003, v89(14), 3701-3712.
60.      Z. Yao and W.H. Ray, Modeling and Analysis of New Processes for Polyester and Nylon Production, AIChE J., 2001, v47(2), 401-412.
61.      K.Z. Yao, and K.B. McAuley, Simulation of Continuous Solid- Phase Polymerization of Nylon 6,6 (II): Processes with Moving Bed Level and Changing Particle Properties, Chem. Eng. Sci., 2001, v56(18), 5327-5342.
62.      K.Z. Yao, K.B. McAuley, D. Berg and E.K. Marchildon, A Dynamic Mathematical Model for Continuous Solid-Phase Polymerization of Nylon 6,6”, Chem. Eng. Sci., 2001, v56(16), 4801-4814.
63.      Z. Yao, B.G. Li, W.J. Wang and Z.R. Pan, “Continuous Thermal Bulk Copolymerization of Styrene and Maleic Anhydride”, J. Appl. Polym. Sci., 1999, v73(5), 615-622.
64.      Z. Yao, B.G. Li, K. Cao and Z.R. Pan, “Semi-continuous Thermal Bulk Copolymerization of Styrene and Maleic Anhydride — Experiments and Reactor Model”, J. Appl. Polym. Sci., 1998, v67(11), 1905-1912.
 
专利
 
1.     姚臻;;吴丽美;杜赞玲;陈洁,同球负载光引发剂和RAFT试剂以制备多重环境响应型毛发状聚合物微球的方法,ZL201110020612.3
2.     陈曦, 范伟伟, 姚臻, 邵之江, 钱积新, 自由基聚合物分子量分布操作条件优化方法, ZL20111000491.6
3.     陈曦, 陈智强, 邵之江, 姚臻, 钱积新, 一种用于聚合物分子量分布计算的多核并行求解方法, ZL201110000456.4
4.     陈智强, 陈曦, 邵之江, 姚臻, 钱积新, 用于聚合物分子量分布求解的图形处理器并行求解方法, ZL201110000445.6
5.     姚臻,曹,陆湛泉,李彦,吴水良,曲邦威,沈之丞,含杂化长支链结构的高熔体强度聚烯烃的制备方法,ZL201010618033.4
6.     ;姚臻;陈洁;杜赞玲,多重环境响应型毛发状聚合物微球及其光引发剂RAFT聚合的制备方法,ZL201010281709.5
7.     ;姚臻;张江山;李本菊;陈慕浪,酸酐酰胺化嵌段梳状共聚物及其制备方法和作为原油降凝减粘剂的用途,ZL201010256489.0
8.     姚臻, , 张江山, 李本菊, 陈慕浪, 酸酐酯化嵌段梳状共聚物及其制备方法和作为原油降凝减粘剂的用途, ZL201010256223.6
9.     , 姚臻, 刘少杰, 戴斌斌, 带极性基团的环烯烃共聚物及其制备方法, ZL200910100771.7
10.   姚臻, 刘赫扬, 张江山, , 高耐热的抗冲共聚组合物及其连续制备方法, ZL200810120347.4
11.   李伯耿, 王文俊, 姚臻, 石正金, 夏燕敏, 陈俭茂, 用于本体聚合的反应器, ZL98110857.1