罗英武课题组

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高翔 副教授,博士,博导

化学工程联合国家重点实验室(浙江大学)
           浙江大学化工系聚合与聚合物工程研究所
           地址:杭州市浙大路38号第十教学大楼4015B房间 (邮编:310027)
           电话:0571-87951280
           传真:0571-87951612
           电子邮件:
gaox@zju.edu.cn

简历

200911-今,浙江大学化学与生物工程学院
2005
-2009年,McMaster University,加拿大,博士
2002
-2005年,天津大学,硕士

1998
-2002年,天津大学,学士

 

研究兴趣

锂离子电池研究

聚合物新材料研发

聚合物膜加工

多形状记忆材料
活性自由基聚合研究

 

 

3D打印多形状记忆智能材料

 多形状记忆智能材料的设计及制备

 

 

基于新型电极粘结剂动力锂电池


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聚烯烃锂电池隔膜挤出拉伸加工

主要在研项目


本征可弹性拉伸锂离子全电池制备及其结构与性能实时分析(国家自然科学基金项目)

导电、导离子、高粘弹性理想电极粘结剂的制备与性能研究(国家自然科学基金项目)

聚合物分子链梯度结构设计实现多形状记忆功能的研究(国家自然科学基金项目)

活性自由基高内相(细)乳液聚合过程研究(国家自然科学基金项目)

解决高比容量锂离子电池寿命过短问题的关键技术研究(浙江省科学技术厅课题)

活性自由基乳液模板聚合法制备高性能聚合物多孔隔膜(教育部博士点基金)

聚合物锂离子电池凝胶电解质的研究(浙江省科学技术厅课题)

辐照交联动力锂电池隔离膜材料的研究(浙江省科学技术厅课题)

 

 授权专利:

  

Block copolymer comprising a block with glass transition temperature higher than 100°C and method for preparing the same,美国专利 US 9,920,156 B2,许少宏,高翔,罗英武,授权日期:2018320

一种硫正极用水基粘结剂及制备方法201610832622.X高翔,李丽红,罗英武,朱世平,授权日期:2018年4月27日,

一种水基电极粘结剂及制备方法,201610671015.X,高翔,郑哲楠,罗英武,张帆,授权日期:2018年2月2日

嵌段共聚物增韧剂及制备方法与应用,ZL201510297485.X,朱月,高翔,罗英武,授权日期:2018112

基于嵌段共聚物的丙烯腈-苯乙烯-丙烯酸酯韧性树脂的制备方法,ZL201510393636.1,黄杰,高翔,罗英武,授权日期:20171031

Poly((meth)acrylic acid-b-styrene-b-butadiene-b-styrene) block copolymer  latex and method for preparing the same, 美国专利,专利号 US 9,328,234 B2,罗英武,魏任重,高翔,授权日期:2016年5月3日

((甲基)丙烯酸-b-苯乙烯-b-(异戊二烯-co-丁二烯)-b-苯乙烯)嵌段共聚物胶乳及制备方法,ZL201410269519.X,高翔,罗英武,授权日期:2016824

Method for preparing porous anti-reflective thin film composed of hollow polymer nanoparticles, 美国专利,专利号 US 9,180,486 B2, 孙志娟,高翔,罗英武,授权日期:20151110

一种辐照交联锂离子电池隔膜及其制备方法, ZL201310196439.1高翔、盛伟、 李伯耿、罗英武、林叶刚、王永常,授权日期:2015429

含玻璃化温度高于100oC嵌段的嵌段共聚物及制备方法,ZL201210243061.1,许少宏,高翔,罗英武,授权日期:2014716

高内相乳液可逆加成断裂链转移聚合制备多孔材料的方法,王安妮,高翔,罗英武,ZL201110370935.5授权日期:201464

一种V型梯度共聚物及其制备方法, ZL201210387662.X,郭云龙,高翔,罗英武,授权日期:2014416

聚苯乙烯-b-聚丁二烯嵌段共聚物纳米胶乳及其制备方法,ZL201210084866.6,魏任重,高翔,罗英武,授权日期:2014129

由聚合物纳米中空胶囊制备超级绝热聚合物材料的方法,ZL201110289648.1,罗英武,高翔,叶长怀,授权日期:201387

聚((甲基)丙烯酸-b-苯乙烯-b-丁二烯-b-苯乙烯)嵌段共聚物胶乳及其制备方法,ZL201210067021.6,罗英武,魏任重,高翔,授权日期:2013925

聚((甲基)丙烯酸-b-丁二烯)嵌段共聚物及其制备方法,ZL201110119838.9,魏任重,高翔,罗英武,授权日期:20121114


 

代表性论文

1. Zhou, A.; Sim, R.; Luo, Y. W.; Gao, X., High-performance stretchable electrodes prepared from elastomeric current collectors and binders. J. Mater. Chem. A 2017, 5, 21550-21559.

2. Liu, D.; Wang, J.; Zhang, Y. B.; Liu, J.; Li, H. M.; Zhou, L.; Wu, S.; Gao, X., Preparation of core-shell structured Au@SiO2 nanocomposite catalyst with Au core size below 2 nm without high-temperature calcination procedure. J. Mater. Sci. 2018, 53, 8086-8097.

3. Wang, S.; Li, J. X.; Qi, M. F.; Gao, X.; Wang, W. J., Toward Maximizing the Mechanical Property of Interconnected Macroporous Polystyrenes Made from High Internal Phase Emulsions. Langmuir 2017, 33, 14295-14303.

4. Li, L.; Wang, Y.; Gao, X.; Zhu, S., Preparation and Evaluation of a New Water-Based Binder for Sulfur Cathode in Lithium-Sulfur Batteries. Journal of Chemical Engineering of Chinese Universities 2017, 31, 669-678.

5. Li, H.; Luo, Y.; Gao, X., Core-shell nano-latex blending method to prepare multi-shape memory polymers. Soft Matter 2017, 13, 5324-5331.

6. Zhu, Y.; Gao, X.; Luo, Y., Core-shell particles of poly(methyl methacrylate)-block-poly(n-butyl acrylate) synthesized via reversible addition-fragmentation chain-transfer emulsion polymerization and the polymer's application in toughening polycarbonate. Journal of Applied Polymer Science 2016, 133.

7. Zheng, Z.; Gao, X.; Luo, Y.; Zhu, S., Employing Gradient Copolymer To Achieve Gel Polymer Electrolytes with High Ionic Conductivity. Macromolecules 2016, 49, 2179-2188.

8. Yan, K.; Gao, X.; Luo, Y., Kinetics of RAFT Emulsion Polymerization of Styrene Mediated by Oligo(Acrylic Acid-b-Styrene) Trithiocarbonate. Aiche Journal 2016, 62, 2126-2134.

9. Li, H.; Gao, X.; Luo, Y., Multi-shape memory polymers achieved by the spatio-assembly of 3D printable thermoplastic building blocks. Soft Matter 2016, 12, 3226-3233.

10. Zhu, Y.; Bi, S.; Gao, X.; Luo, Y., Comparison of RAFT Ab Initio Emulsion Polymerization of Methyl Methacrylate and Styrene Mediated by Oligo(methacrylic acid-b-methyl methacrylate) Trithiocarbonate Surfactant. Macromolecular Reaction Engineering 2015, 9, 503-511.

11. Yan, K.; Gao, X.; Luo, Y., Well-Defined High Molecular Weight Polystyrene with High Rates and High Livingness Synthesized via Two-Stage RAFT Emulsion Polymerization. Macromolecular Rapid Communications 2015, 36, 1277-1282.

12. Yan, K.; Gao, X.; Luo, Y., Correlation between polydispersities of molecular weight distribution and particle size distribution in RAFT Emulsion Polymerization of Styrene. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1848-1853.

13. Luo, Y.; Wang, A.-N.; Gao, X., One-pot interfacial polymerization to prepare PolyHIPEs with functional surface. Colloid and Polymer Science 2015, 293, 1767-1779.

14. Guo, Y.; Gao, X.; Luo, Y., Suppressing the Long-Chain Branching in the Synthesis of Poly(styrene-b-butyl acrylate-b-styrene) in RAFT Emulsion Polymerization by Tuning the Interfacial Properties. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1464-1473.

15. Guo, Y.; Gao, X.; Luo, Y., Mechanical Properties of Gradient Copolymers of Styrene and n-Butyl Acrylate. Journal of Polymer Science Part B-Polymer Physics 2015, 53, 860-868.

16. Gao, X.; Sheng, W.; Wang, Y.; Lin, Y.; Luo, Y.; Li, B.-G., Polyethylene battery separator with auto-shutdown ability, thermal stability of 220 degrees C, and hydrophilic surface via solid-state ultraviolet irradiation. Journal of Applied Polymer Science 2015, 132.

17. Huang, J.; Zhao, S.; Gao, X.; Luo, Y.; Li, B., Ab Initio RAFT Emulsion Copolymerization of Styrene and Acrylonitrile. Industrial & Engineering Chemistry Research 2014, 53, 7688-7695.

18. Huang, J.; Zhao, S.; Gao, X.; Luo, Y.; Li, B., RAFT Ab Initio Emulsion Polymerization of Styrene Using Poly(acrylic acid)-b-polystyrene Trithiocarbonate of Various Structures as Mediator and Surfactant. Macromolecular Reaction Engineering 2014, 8, 696-705.

19. Guo, Y.; Zhang, J.; Xie, P.; Gao, X.; Luo, Y., Tailor-made compositional gradient copolymer by a many-shot RAFT emulsion polymerization method. Polymer Chemistry 2014, 5, 3363-3371.

20. Luo, Y.; Guo, Y.; Gao, X.; Li, B.-G.; Xie, T., A General Approach Towards Thermoplastic Multishape-Memory Polymers via Sequence Structure Design. Advanced Materials 2013, 25, 743-748.

21. Zhou, D.; Gao, X.; Wang, W.-j.; Zhu, S., Termination of Surface Radicals and Kinetic Modeling of ATRP Grafting from Flat Surfaces by Addition of Deactivator. Macromolecules 2012, 45, 1198-1207.

22. Ye, X.; Luo, Y.; Gao, X.; Zhu, S., Design and evaluation of a thermochromic roof system for energy saving based on poly(N-isopropylacrylamide) aqueous solution. Energy and Buildings 2012, 48, 175-179.

23. Luo, Y.; Wang, A.-N.; Gao, X., Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 2012, 8, 1824-1830.

24. Luo, Y.; Wang, A.-N.; Gao, X., Miniemulsion template polymerization to prepare a sub-micrometer porous polymeric monolith with an inter-connected structure and very high mechanical strength. Soft Matter 2012, 8, 7547-7551.

25. Gao, X.; Zhu, S., Modeling Analysis of Chain Transfer in Reversible Addition-Fragmentation Chain Transfer Polymerization. Journal of Applied Polymer Science 2011, 122, 497-508.

26. Feng, W.; Gao, X.; McClung, G.; Zhu, S.; Ishihara, K.; Brash, J. L., Methacrylate polymer layers bearing poly(ethylene oxide) and phosphorylcholine side chains as non-fouling surfaces: In vitro interactions with plasma proteins and platelets. Acta Biomaterialia 2011, 7, 3692-3699.

27. Gao, X.; Zhu, S.; Sheardown, H.; Brash, J. L., Nanoscale patterning through self-assembly of hydrophilic block copolymers with one chain end constrained to surface. Polymer 2010, 51, 1771-1778.

28. Gao, X.; Feng, W.; Zhu, S.; Sheardown, H.; Brash, J. L., Kinetic Modeling of Surface-Initiated Atom Transfer Radical Polymerization. Macromolecular Reaction Engineering 2010, 4, 235-250.

29. Gao, X.; Kucerka, N.; Nieh, M.-P.; Katsaras, J.; Zhu, S.; Brash, J. L.; Sheardown, H., Chain Conformation of a New Class of PEG-Based Thermoresponsive Polymer Brushes Grafted on Silicon as Determined by Neutron Reflectometry. Langmuir 2009, 25, 10271-10278.

30. Gao, X.; Feng, W.; Zhu, S.; Sheardown, H.; Brash, J. L., A facile method of forming nanoscale patterns on poly(ethylene glycol)-based surfaces by self-assembly of randomly grafted block copolymer brushes. Langmuir 2008, 24, 8303-8308.

31. Gao, X.; Liu, L.; Liu, X.; Zhang, B.; Lin, T., Permeation of Compressed and Supercritical Fluids through Porous Membranes. Journal of Chemical Engineering of Chinese Universities 2005, 19, 577-582.