罗英武课题组

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高翔 副教授,博士,博导

化学工程联合国家重点实验室(浙江大学)
浙江大学化工系聚合与聚合物工程研究所
地址:杭州市浙大路38号第十教学大楼4015B房间 (邮编:310027
电话:0571-87951280
传真:0571-87951612
电子邮件:
gaox@zju.edu.cn

简历

 

200911-今,浙江大学化学与生物工程学院
2005
-2009年,McMaster University,加拿大,博士
2002
-2005年,天津大学,硕士

1998
-2002年,天津大学,学士

 

研究兴趣

 

锂离子电池研究

多孔聚合物材料的制备研究

多形状记忆材料的制备
活性自由基聚合研究
聚合物锂硫电池

 

 

3D打印多形状记忆智能材料

 多形状记忆智能材料的设计及制备

 

 

基于新型电极粘结剂动力锂电池

  

 

 

主要在研项目

 

导电、导离子、高粘弹性理想电极粘结剂的制备与性能研究(国家自然科学基金项目)

聚合物分子链梯度结构设计实现多形状记忆功能的研究(国家自然科学基金项目)

活性自由基高内相(细)乳液聚合过程研究(国家自然科学基金项目)

新结构TPS 的活性/可控聚合法制备及应用基础(科技部973项目子课题)

解决高比容量锂离子电池寿命过短问题的关键技术研究(浙江省科学技术厅课题)

活性自由基乳液模板聚合法制备高性能聚合物多孔隔膜(教育部博士点基金)

聚合物锂离子电池凝胶电解质的研究(浙江省科学技术厅课题)

辐照交联动力锂电池隔离膜材料的研究(浙江省科学技术厅课题)

 

 授权专利:

  

一种辐照交联锂离子电池隔膜及其制备方法,ZL201310196439.1
一种V型梯度共聚物及其制备方法, ZL201210387662.X

含玻璃化温度高于100oC嵌段的嵌段共聚物及制备方法,ZL201210243061.1
聚苯乙烯-b-聚丁二烯嵌段共聚物纳米胶乳及其制备方法,ZL201210084866.6
高内相乳液可逆加成断裂链转移聚合制备多孔材料的方法ZL201110370935.5
聚((甲基)丙烯酸-b-苯乙烯-b-丁二烯-b-苯乙烯)嵌段共聚物胶乳及其制备方法,ZL201210067021.6

由聚合物纳米中空胶囊制备超级绝热聚合物材料的方法,ZL201110289648.1
聚((甲基)丙烯酸-b-丁二烯)嵌段共聚物及其制备方法,ZL201110119838.9

 

代表性论文

Employing Gradient Copolymer to Achieve Gel Polymer Electrolytes with High Ionic Conductivity, Zheng Z.N.; Gao, X.; Luo, Y.W.; Zhu, S.P., Macromolecules, 2016, (In Press)

Multi-shape memory polymers achieved by spatio-assembly of 3D printable thermoplastic building blocks, Li H.Z.; Gao, X.; Luo, Y.W.; Soft Matter, 2016, (In Press)

Core-shell particles of poly(methyl methacrylate)-block-poly(n-butyl acrylate) synthesized via reversible addition-fragmentation chain-transfer emulsion polymerization and the polymer's application in toughening polycarbonate, Journal of Applied Polymer Science, 2016, 133(1).

Suppressing the long-chain branching in the synthesis of poly(styrene-b-butyl acrylate-b-styrene) in RAFT emulsion polymerization by tuning the interfacial properties. Guo Y. L.; Gao X.; Luo, Y. W.; Journal of Polymer Science Part A: Polymer Chemistry 2015, 53(12), 1464-1473.

 Mechanical Properties of Gradient Copolymers of Styrene and n-Butyl Acrylate. Guo Y. L.; Gao X.; Luo, Y. W.; Journal of Polymer Science Part B: Polymer Physics 2015, 53(12), 860-868.

Correlation between polydispersities of molecular weight distribution and particle size distribution in RAFT emulsion polymerization of styrene. Yan K.; Gao X.; Luo, Y. W.; Journal of Polymer Science, Part A: Polymer Chemistry, 2015, 53(16), 1848-1853.

One-pot interfacial polymerization to prepare PolyHIPEs with functional surface. Luo, Y. W.; Wang, A. N.; Gao, X.; Colloid and Polymer Science, 2015, 293(6), 1767-1779.

Polyethylene battery separator with auto-shutdown ability, thermal stability of 220°C and hydrophilic surface via solid-state ultraviolet irradiation. Gao, X.;  Sheng W., Wang Y. C.; Lin Y. G.; Luo Y. W.; Li B. G.; Journal of Applied Polymer Science, 2015, 132(26).

 Huang, J.; Zhao, S.; Gao, X.; Luo, Y. W.; Li, B. G. RAFT Ab Initio Emulsion Polymerization of Styrene Using Poly(acrylic acid)-b-polystyrene Trithiocarbonate of Various Structures as Mediator and Surfactant. Macromolecular Reaction Engineering 2014, 8 (10), 696-705.

Huang, J.; Zhao, S. M.; Gao, X.; Luo, Y. W.; Li, B. G. Ab Initio RAFT Emulsion Copolymerization of Styrene and Acrylonitrile. Industrial & Engineering Chemistry Research 2014, 53 (18), 7688-7695.

Guo, Y. L.; Zhang, J. H.; Xie, P. L.; Gao, X.; Luo, Y. W. Tailor-made compositional gradient copolymer by a many-shot RAFT emulsion polymerization method. Polymer Chemistry 2014, 5 (10), 3363-3371.

Luo, Y. W.; Guo, Y. L.; Gao. X.; Li, B.G.; Xie, T. A general approach towards thermoplastic multishape-memory polymers via sequence structure design. Advanced Materials 2013, 25(5), 743-748.

Luo, Y. W.; Wang, A. N.; Gao, X. Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 2012, 8 (6), 1824-1830.

Luo, Y. W.; Wang, A. N.; Gao, X. Miniemulsion template polymerization to prepare sub-micrometer porous polymeric monolith with inter-connected structure and very high mechanical strength. Soft Matter 2012, 8 (29), 3547-3551.

Ye, X. W.; Luo, Y. W.; Gao, X.; Zhu, S. P. Design and evaluation of a thermochromic roof system for energy saving based on poly(N-isopropylacrylamide) aqueous solution. Energy and Buildings 2012, 48, 175-179.

Zhou, D. P.; Gao, X.; Wang, W. J.; Zhu, S. P. Termination of Surface Radicals and Kinetic Modeling of ATRP Grafting from Flat Surfaces by Addition of Deactivator. Macromolecules 2012, 45 (3), 1198-1207.

Gao, X.; Zhu, S. P. Modeling Analysis of Chain Transfer in Reversible Addition-Fragmentation Chain Transfer Polymerization. Journal of Applied Polymer Science 2011, 122 (1), 497-508.

Feng, W.; Gao, X.; McClung, G.; Zhu, S. P.; Ishihara, K.; Brash, J. L. Methacrylate polymer layers bearing poly(ethylene oxide) and phosphorylcholine side chains as non-fouling surfaces: In vitro interactions with plasma proteins and platelets. Acta Biomaterialia 2011, 7 (10), 3692-3699.

Gao, X.; Zhu, S. P.; Sheardown, H.; Brash, J. L. Nanoscale patterning through self-assembly of hydrophilic block copolymers with one chain end constrained to surface. Polymer 2010, 51 (8), 1771-1778.

Gao, X.; Feng, W.; Zhu, S. P.; Sheardown, H.; Brash, J. L. Kinetic Modeling of Surface-Initiated Atom Transfer Radical Polymerization. Macromolecular Reaction Engineering 2010, 4 (3-4), 235-250.

Gao, X.; Kucerka, N.; Nieh, M. P.; Katsaras, J.; Zhu, S. P.; Brash, J. L.; Sheardown, H. Chain Conformation of a New Class of PEG-Based Thermoresponsive Polymer Brushes Grafted on Silicon as Determined by Neutron Reflectometry. Langmuir 2009, 25 (17), 10271-10278.

Gao, X.; Feng, W.; Zhu, S. P.; Sheardown, H.; Brash, J. L. A facile method of forming nanoscale patterns on poly(ethylene glycol)-based surfaces by self-assembly of randomly grafted block copolymer brushes. Langmuir 2008, 24 (15), 8303-8308.