Prof. Tao XIE's Group

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Publication

After founding the group at ZJU from Jul. 2013:

54. Fang ZZ, Shi YP, Zhang YH,* Zhao Q, Wu JJ.*

Reconfigurable polymer networks for digital light processing 3D printing.

ACS Appl. Mater. Interfaces, 2021, 13, 15584-15590.

53. Shi YP, Fang GQ,* Cao ZL, Shi FZ, Zhao Q, Fang ZZ,* Xie T.

Digital light fabrication of reversible shape memory polymers.

Chem. Eng. J., 2021, 426, 131306.

52. Peng WJ, Zhang GG, Zhao  Q, Xie T.*

Autonomous off-equilibrium morphing pathways of a supramolecular shape-memory polymer.

Adv. Mater., 2021, 2102473.

51. Xu Y, Li Y, Zheng N*, Zhao Q, Xie T*.

Transparent origami glass.

Nat. Commun, 2021, 12, 4261.

50. You DQ,# Chen GC,# Liu C,# Ye X, Wang SL, Dong MY, Sun MY, He JX, Yu XW, Ye GC, Wu JJ, Wu JJ, Zhao Q,* Xie T, Yu MF,* and Wang HM.*

4D printing of multi-responsive membrane for accelerated in vivo bone healing via remote regulation of stem cell fate.

Adv. Funct. Mater., 2021, 2103920.

49. Deng SH,# Huang LM,# Wu JJ, Pan PJ, Zhao Q,* Xie T. 

Bioinspired dual mode temporal communication via digital programmable phase change materials.

Adv. Mater., 2021, 2008119.

48. Chen GC, Jin BJ, Zhao Q, Xie T*. 
Photo-driven metallo-supramolecular stress-free reversible shape mempry polymer.
J. Mater. Chem. A, 2021, 9, 6827-6830.

47. Ni C, Chen D, Zhang Y, Xie T, Zhao Q.*  
Autonomous shapeshifting hydrogels via temporal programming of photoswitchable dynamic network.
Chem. Mater., 2021, 33, 2046-2053.

46. Zheng N, Xu Y, Zhao Q, Xie T.* 
Dynamic covalent polymer networks: A molecular platform for designing functions beyond chemical recycling and self-healing.
Chem. Rev., 2021, 121, 1716-1745.

45. Choi Y S, Hsueh Y Y, Koo J, Yang Q, Avila R, Hu BW, Xie ZQ, Lee G, Zheng N, Liu C, Xu YM, Lee Y J, Zhao WK, Fang J, Deng YJ, Lee S M, Vázquez-Guardado A, Stepien I, Yan Y, Song J W, Haney C, Oh Y S, Liu WT, Yun H J, Banks A, MacEwan M R, Ameer G A, Ray W Z, Huang YG, Xie T, Franz C K, Li S,* Rogers J A.*
Stretchable, dynamic covalent polymers for soft, long-lived bioresorbable electronic stimulators designed to facilitate neuromuscular regeneration.
Nat. Commun., 2020, 11, 5990.

44. Xie T and Vogt B D.
A virtual special issue on self-healing materials.
ACS Appl. Mater. Interfaces, 2020, 12, 49277-49280.

43. Miao WS, Zou WK, Jin BJ, Ni CJ, Zheng N, Zhao Q, Xie T.* 
On demand shape memory polymer via light regulated topological defects in a dynamic covalent network.
Nat. Commun. 2020, 11, 4257.

42. Liu KK,# Zhang Y,# Cao HQ, Liu HN, Geng YH, Yuan WH, Zhou J, Wu ZL, Shan GR, Bao YZ, Zhao Q,* Xie T, Pan PJ.* 
Programmable reversible shape transformation of hydrogels based on transient structural anisotropy.
Adv. Mater.
, 2020, 2001693.

41. Zou WK,# Jin BJ,# Wu Y, Song HJ, Luo YW, Huang FH, Qian J, Zhao Q,* Xie T.*
Light-triggered topological programmability in a dynamic covalent polymer network.
Sci. Adv., 2020, 6, eaaz2362.

40. Peng WJ,# Zhang GG,# Liu J,* Nie S, Wu Y, Deng SH, Fang GQ, Zhou J, Song JZ, Qian J, Pan PJ, Zhao Q, Xie T.*
Light-coded digital crystallinity patterns toward bioinspired 4D transformation of shape-memory polymers.
Adv. Funct. Mater., 2020, 30, 2000522.

39. Fang ZZ,# Song HJ,# Zhang Y, Jin BJ, Wu JJ, Zhao Q,* Xie T.*
Modular 4D printing via interfacial welding of digital light-controllable dynamic covalent polymer networks.
Matter, 2020, 2, 1187-1197.

38. Miao WS, Zou WK,* Luo YW, Zheng N, Zhao Q, Xie T.* 

Structural tuning of polycaprolactone based thermadapt shape memory polymer.

Polym. Chem.,  2020, 11, 1369-1374.

37. Park J K, Nan KW, Luan HW, Zheng N, Zhao Shiwei, Zhang H, Cheng X, Wang HL, Li K, Xie T, Huang YG, Zhang YH,* Kim S,* Rogers JA.* 
Remotely triggered assembly of 3D mesosrtuctures through shape-memory effects. 
Adv. Mater.,  2019, 31, 1905715.

36. Zhang Y, Huang LM, Song HJ, Ni CJ, Wu JJ,* Zhao Q, Xie T.* 
4D printing of a digital shape memory polymer with tunable high performance.
ACS Appl. Mater. Interfaces, 2019, 11, 32408-32413.

35. Hou YK, Fang GQ, Jiang YB, Song HJ, Zhang YH,* Zhao Q.*
Emulsion lyophilization as a facile pathway to fabricate stretchable polymer foams enabling multishape memory effect and clip application. 
ACS Appl. Mater. Interfaces, 2019, 11, 32423-32430.

34. Deng SH, Wu JJ,* Dickey MD, Zhao Q, Xie T.*
Rapid open‐air digital light 3D printing of thermoplastic polymer.
Adv. Mater., 2019, 31, 1903970.

33. Song HJ, Fang ZZ, Jin BJ, Pan PJ, Zhao Q,*  Xie T.*
Synergetic chemical and physical progrmming for reversible shape memory effect in a dynamic covalent network with two crystalline phases.
ACS Macro Lett., 2019, 8, 682.

32. 陈冠聪, 方子正, 候宇坤, 童张法, 赵骞.*

玻璃化转变温度可区域数字化调控的形状记忆聚合物.

高分子学报, 2019, 50, 311.

31. Zhang Y, Zheng N, Cao Y, Wang F, Wang P, Ma Y, Lu B, Hou G, Fang Z, Liang Z, Yue M, Li Y, Chen Y, Fu J, Wu J, Xie T, Feng X.*
Climbing-inspired twining electrodes using shape memory for peripheral nerve stimulation and recording.
Sci. Adv., 2019, 5, eaaw1066.

30. Wang H, Zhu CN, Zeng H, Ji XF, Xie T, Yan XZ,*Wu ZL,* Huang FH.*
Reversible ion-conducting switch in a novel single-ion supramolecular hydrogel enabled by photoresponsive host–guest molecular recognition.
Adv. Mater., 2019, 31, 1807328.

29. Du GL, Mao AR, Yu JH, Hou JJ, Zhao NF, Han JK, Zhao Q, Gao WW, Xie T,*  Bai H.*
Nacre-mimetic composite with intrinsic self-healing and shape-programming capability.
Nat. Commun., 2019, 10, 800.

28. Chen D, Zhang Y, Ni CJ, Ma C, Yin J, Bai H, Luo YW, Huang FH, Xie T, Zhao Q.*
Drilling by light: ice-templated photo-patterning enabled by a dynamically crosslinked hydrogel.
Mater. Horiz., 2019, 6, 1013.

27. Zheng N,#  Hou JJ,#  Zhao HB, Wu JJ, Luo YW, Bai H, Rogers JA, Zhao Q,* Xie T.*
Mechano-plastic pyrolysis of dynamic covalent polymer network toward hierarchical 3D ceramics.
Adv. Mater., 2019, 31, 1807326.

26. Wang XJ, Guo XG, Ye JL, Zheng N,  Kohli P, Choi D, Zhang Y, Xie Z, Zhang Q, Luan H, Nan K, Kim BH, Xu YM, Shan XW, Bai WB, Sun RJ, Wang ZZ, Jang H, Zhang F, Ma YJ, Xu Z, Feng X, Xie T, Huang YG, Zhang YH,* Rogers JA.*
Freestanding 3D mesostructures, functional devices, and shape-programmable systems based on mechanically induced assembly with shape memory polymers.
Adv. Mater., 2019, 31, 1805615.

25. Zhang GG, Peng WJ, Wu JJ, Zhao Q, Xie, T.*
Digital coding of mechanical stress in a dynamic covalent shape memory polymer network. 
Nat. Commun., 2018, 9, 4002.

24. Wu JJ, Huang LM, Zhao Q, Xie T.*
4D printing: history and recent progress.
Chinese J. Polym. Sci., 2018, 36, 563.

23. Cao Y,# Zhang GG,# Zhang YC, Yue MK, Chen Y, Cai SS, Xie T,* Feng X.*
Direct fabrication of stretchable electronics on a polymer substrate with process-integrated programmable rigidity.
Adv. Funct. Mater., 2018, 28,1804604.

22. Jin BJ, Song HJ, Jiang RQ, Song JZ, Zhao Q* Xie T.*
Programming a crystalline shape memory polymer network with thermo- and photo-reversible bonds toward a single component soft robot.
Sci. Adv., 2018, 4, eaao3865.

21. Yang LP, Zhang GG, Zheng N, Zhao Q,* Xie T.*
A metallosupramolecular shape-memory polymer with gradient thermal plasticity
Angew. Chem. Int. Ed., 2017, 56, 12599.

20. Zheng N, Xie T.*
Thermadapt shape memory polymer.
Acta Polymerica Sinica., 2017, 11, 46.

19. Fang ZZ,# Zheng N,# Zhao Q,* Xie T.*
Healable, reconfigurable, reprocessable thermoset shape memory polymer with highly tunable topological rearrangement kinetics.
ACS Appl. Mater. Interfaces, 2017, 9, 22077.

18. Wong TW, Wu JJ, Yang M, Kadir MRA, Wahit MU, Zhao Q.*
Multifunctional shape-memory foams with highly tunable properties via organo-phase cryopolymerization.
J. Mater. Chem. A, 2017, 5, 9793.

17. Zou WK, Dong JT, Luo YW, Zhao Q,* Xie T*.
Dynamic covalent polymer networks: from old chemistry to modern day innovations.
Adv. Mater., 2017, 29, 1606100.

16. Zheng N, Hou JJ, Xu Y, Fang ZZ, Zou WK, Zhao Q,* Xie T.*
Catalyst-free thermoset polyurethane with permanent shape reconfigurability and highly tunable triple-shape memory performance.
ACS Macro Lett., 2017, 6, 326.

15. Chen D,# Xia XH,# Wong TW, Bai H, Behl M, Zhao Q,* Lendlein A, Xie T. (# equal contribution)
Omnidirectional shape memory effect via lyophilization of PEG hydrogels.
Macromol. Rapid Commun., 2017, 38, 1600746.

14. Zheng N, Huang Y, Zhao Q, Feng X, Xie T.*
Shape memory polymers for flexible electronics.
SCIENTIA SINICA Physica, Mechanica&Astronomica, 2016, 46, 020000.

13. Huang Y, Zheng N, Cheng ZQ, Chen Y, Lu BW, Xie T,* Feng X.*
Direct laser writing-based programmable transfer printing via bioinspired shape memory reversible adhesive.
ACS Appl. Mater. Interfaces, 2016, 8, 35628.

12. Huang LM, Jiang RQ, Wu JJ, Song JZ, Bai H, Li BG, Zhao Q,* Xie T.*
Ultrafast digital printing toward 4D shape changing materials.
Adv. Mater., 2017, 29, 1605390.

11. Yang M, Wong TW, Wu JJ, Bai H, Xie T, Zhao Q.*
Controlling three dimensional ice template via two dimensional surface wetting.
AIChE J. 2016, 62, 4186.

10. Zhao Q, Yang XX, Ma CX, Chen D, Bai H, Li TF,* Yang W, Xie T.*
A bioinspired reversible snapping hydrogel assembly.
Mater. Horiz., 2016, 3, 422. Highlighted by Chemistry World and Scientific American. Chosen as inside back cover.

9. Zheng N, Fang ZZ, Zou WK, Zhao Q,* Xie T.*
Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation.
Angew. Chem. Int. Ed., 2016, 55, 11421. Very Important Paper. Chosen as inside cover.

8. Zhang GG, Zhao Q,* Yang LP, Zou WK, Xi XY, Xie T.*
Exploring dynamic equilibrium of Diels-Alder reaction for solid state plasticity in remoldable shape memory polymer network.
ACS Macro Lett., 2016, 5, 805.

7. Zhao Q, Zou WK, Luo YW, Xie T.*
Shape memory polymer network with thermally distinct elasticity and plasticity.
Sci. Adv., 2016, e1501297. Highlighted by Science News, Nature, Wall Street Journal, Chemistry World, Popular Mechanics, and others.

6. Zhang GG,# Zhao Q,# Zou WK, Luo YW, Xie T.* (# equal contribution)
Unusual aspects of supramolecular network: plasticity to elasticity, ultrasoft shape memory, and dynamic mechanical properties.
Adv. Funct. Mater., 2016, 26, 931.

5. Zhao Q, Qi HJ, Xie T.*
Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding.
Prog. Polym. Sci., 2015, 49-50, 79.

4. Zheng N, Fang GQ, Cao ZL, Zhao Q, Xie T.*
High strain epoxy shape memory polymer.
Polym. Chem., 2015, 6, 3046.

3. Ma CX, Li TF, Zhao Q,* Yang XX, Wu JJ, Luo YW, Xie T.
Supramolecular Lego assembly towards three-dimensional multi-responsive hydrogels.
Adv. Mater., 2014, 26, 5665. Highlighed by MaterialsViewsChina.

2. Xie T,* Li JJ, Zhao Q.
Hidden thermoreversible actuation behavior of nafion and its morphological origin.
Macromolecules, 2014, 47, 1085.

1. Wu JJ, Zhao Q,* Liang CZ, Xie T.
Enzymatically degradable oxidized dextran-chitosan hydrogels with an ansiotropic aligned porous structure.
Soft Matter, 2013, 9, 11136.


Before founding the group:

22. Xie T.*
Tunable polymer multi-shape memory effect.
Nature, 2010, 464, 267. Highlighted by MIT Tech Review, C&E news, Chemistry world, New Scientist, MRS 369, C&I news, Science News, Tech News Daily, and others.

21. Eisenhaure JD, Xie T, Varghess S, Kim S.*
Microstructured shape memory polymer surfaces with reversible dry adhesion.
ACS Appl. Mater. Interfaces, 2013, 5,7714.

20. Luo K, Xie T, Rzayev J.*
Synthesis of themally demally degradable epoxy adhesive.
J. Polym. Sci., Part A: Polym. Chem., 2013, 51, 4299.

19. Xu H, Yu C, Wang S, Malyarchuk V, Xie T,* Rogers J.*
Deformable, programmable, and shape-memorizing micro-optics.
Adv. Func. Mater., 2013, 23, 3299. Highlighted by Nanowerk, MRS 369, and others.

18. Chen C, Chiang C, Lai C, Xie T, Yang S.*
Buckling-Based Strong Dry Adhesives Via Interlocking.
Adv. Func. Mater., 2013, 23, 3813.

17. Luo Y, Guo Y, Gao X,* Li B, Xie T.
A general approach towards thermoplastic multishape-memory polymers via sequence structure design.
Adv. Mater., 2013, 25, 743.

16. Xie T,* Page K.*
Eastman S, Strain based temperature memory effect for Nafion and its molecular origin.
Adv. Func. Mater., 2011, 21, 2057.

15. Xie T,*
Recent advances in polymer shape memory.
Polymer, 2011, 52, 4895. Invited Feature Article.

14. He Z, Satarkar N, Xie T,* Cheng YT, Hilt Z.*
Remote controlled multi-shape polymer nanocomposites with selective radiofrequency actuations.
Adv. Mater., 2011, 23, 3192.

13. Xie T,* Xiao XC, Li J, Wang R.
Encoding localized strain history through wrinkle based diffraction colors.
Adv. Mater., 2010, 22, 4390. Cover Art.

12. Li J, Xie T.*
Significant impact of thermo-mechanical conditions on polymer triple-shape memory effect.
Macromolecules, 2011, 44, 175.

11. Li J, An Y, Huang R, Jiang H, Xie T.*
Unique aspects of a shape memory polymer as the substrate for surface wrinkling.
ACS Appl. Mater. Interfaces, 2012, 4, 598.

10. Li J, Rodgers W, Xie T.*
Semi-crystalline based two-way reversible shape memory elastomer.
Polymer, 2011,52, 3520.

9. Xiao XC,* Xie T,* Cheng YT.
Self-healable graphene polymer composites.
J. Mater. Chem., 2010, 20, 3508. Invited contribution to special theme issue on Actively moving polymers.

8. Wang RM, Xie T.*
Shape memory- and hydrogen bonding- based strong reversible adhesives.
Langmuir, 2010, 26, 2999. Most accessed article, Highlighted by MIT Tech Review (Super Velcro).

7. Rousseau IA,* Xie T.
Shape memory epoxy: composition, structure, properties and shape memory performances.
J. Mater. Chem., 2010, 20, 3431. Invited contribution to special theme issue on Actively moving polymers.

6. Wang RM, Xie T.*
Macroscopic evidence of strong cation-pi interaction in a synthetic polymer system.
Chem. Commun., 2010, 46, 1341.

5. Wang RM, Xiao XC, Xie T.*
Viscoelastic behavior and force nature of thermo-reversible dry adhesives.
Macromol. Rapid Commun., 2010, 31, 295.

4. Kim S, Sitti M,* Xie T,* Xiao XC.
Reversible dry adhesives with thermally controllable adhesion.
Soft Matter, 2009, 5, 3689.

3. Xie T,* Xiao XC, Cheng YT.
Achieving triple-shape memory effect in polymer bilayers.
Macromol. Rapid Commun., 2009, 30, 1823.

2. Xie T,* Rousseau I.
Facile tailoring of the transformation temperatures of epoxy shape memory polymers.
Polymer, 2009, 50, 1852.

1. Xie T,* Xiao XC.
Self-peeling reversible dry adhesive system.
Chem. Mater., 2008, 20, 2866.


Smart Hydrogels

10. Wu JJ, Ren Y, Sun JZ, Feng LF.*
Carbon Nanotube-coated macroporous poly(N-isopropylacrylamide) hydrogel and its electrosensitivity.
ACS Appl. Mater. Interfaces, 2013, 5, 3519.

9. Wu JJ, Lin YT, Sun JZ.*
Anisotropic volume change of poly(N-isopropylacrylamide)-based hydrogels with an aligned dual-network microstructure.
J. Mater. Chem., 2012, 22, 17449.

8. Zhang JJ, Wu JJ, Sun JZ,* Zhou QY.
Temperature-sensitive bending of bigel strip bonded by macroscopic molecular recognition.
Soft Matter, 2012, 8, 5750.

7. Wu JJ, Zhao Q, Sun JZ,* Zhou QY.
Preparation of poly (ethylene glycol) aligned porous cryogels using unidirectional freezing technique.
Soft Matter, 2012, 8, 3620.

6. Su YJ, Zhao Q*, Sun JZ, Lin YT.
Synthesis and Characterizations of biodegradable macroporous cryogels crosslinked by chitosan oligosaccharide-graft-acrylic acid.
Soft Matter, 2012, 8, 4382.

5. Zhao Q, Sun JZ,* Wu XF, Lin YT.
Macroporous double-network cryogels: formation mechanism, enhanced mechanical strength and temperature/pH dual sensitivity.
Soft Matter, 2011, 7, 4284.

4. Zhao Q, Sun JZ,* Lin YT, Zhou QY.
Study of the properties of hydrolyzed polyacrylamide hydrogels with various pore structures and rapid pH-sensitivities.
React. Funct. Polym., 2010, 70, 620.

3. Zhao Q, Sun JZ,* Ling QC, Zhou QY.
Synthesis of Macroporous Thermosensitive hydrogels: a novel method of controlling pore size.
Langmuir, 2009, 25, 3249.

2. Zhao Q, Sun JZ,* Ling QC, Zhou QY.
Effect of 1,4-dioxane on synthesis of macroporous Poly(N-isopropylacrylamide) hydrogels.
J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 6594.

1. Zhao Q, Sun JZ,* Ren H, Ling QC, Zhou QY.
Horseradish peroxidase immobilized in macroporous hydrogel for acrylamide polymerization.
J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 2222.